OST or Offline Storage Files represent the user's mailbox data in offline mode on the local machine upon registration with Exchange Server using Microsoft Outlook. It is automatically created on the first use of Microsoft Outlook upon connectivity with the server. Once the file is created, the data is synchronized with the email server so that it is available offline as well in case of disconnectivity from the email server.
Files with XLSM extension is a type of Spreasheet files that support Macros. From application point of view, a Macro is set of instructions that are used for automating processes. A macro is used to record the steps that are performed repeatedly and facilitates performing the actions by running the macro again. Macros are programmed with Microsoft's Visual Basic for Applications (VBA) from within the Excel Workbook using the Visual Basic Editor and can be run/debug directly from there.
You can also convert OST into many other file formats. Please see the complete list below.