Files with .PST extension represent Outlook Personal Storage Files (also called Personal Storage Table) that store variety of user information. User information is stored in folders of different types that include emails, calendar items, notes, contacts, and several other file formats. PST files are used for archiving emailing data offline that can be later loaded and viewed in various applications.
Files with OTT extension represent template documents generated by applications in compliance with the OASIS' OpenDocument standard format. These are created with word processor applications such as free OpenOffice Writer and can hold settings that can be used to generate new documents from these template files. These settings include page margins, borders, headers, footers, and other page settings. Such templates are used in official documents such as company letterheads and standardized forms.
You can also convert PST into many other file formats. Please see the complete list below.